Publications

§§§ “TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η2-TEMPO)2CrX (X = Cl, TEMPO)“
Ann K. Kayser, Peter T. Wolczanski, Thomas R. Cundari, Melissa M. Bollmeyer, Kyle M. Lancaster, and Samantha N. MacMillan Chem. Commun. 2022, 58, 9818-9821. [Link]
§§§ “Attempts at generating metathesis-active Fe(IV) and Co(IV) complexes via the reactions of (silox)2M(THF)2, [(silox)3M][Na(THF)2] (M = Fe, Co), and related species with propellanes and triphenylboron“
George, G. M.; Wolczanski, P. T.; MacMillan, S. N. Polyhedron 2022, 215, 115656. [Link]
§§§ “Reversible C–C Bond Formation, Halide Abstraction, and Electromers in Complexes of Iron Containing Redox-Noninnocent Pyridine-imine Ligands“
Pokhriyal, D.; Heins, S. P.; Sifri, R. J.; Gentekos, D. T.; Coleman, R. E.; Wolczanski, P. T.; Cundari, T. R.; Fors, B. P.; Lancaster, K. M.; MacMillan, S. N. Inorg. Chem. 2021, 60 (24), 18662-18673. [Link]
§§§ “Propellanes as Drop-​In ROMP Initiators“
George, G. M.; Wolczanski, P. T.; MacMillan, S. N. Organometallics 2021, 40, 3389–3396. [Link]
§§§ “Unrealized concepts of masked alkylidenes in (PNP)FeXY systems and alternative approaches to LnXmFe(IV)=CHR“
George, G. M.; Wolczanski, P. T.; MacMillan, S. N.; Cundari, T. R. Polyhedron 2020, 181, 114460. [Link]
§§§ “Oxidative Additions to Ti(IV) in [(dadi)​4-]​Ti(IV)​(THF) Involve Carbon-​Carbon Bond Formation and Redox-​Noninnocent Behavior“
               Heins, S. P.; Zhang, B.; MacMillan, S. N.; Cundari, T. R.; Wolczanski, P. T. Organometallics 2019, 38, 1502-1515. [Link]
       
§§§ “Azaallyl-​derived ring formation via redox coupling in first row transition metals“
               Hulley, E. B.; Heins, S. P.; Wolczanski, P. T.; Lancaster, K. M.; Lobkovsky, E. B. Polyhedron 2019, 158, 225-233. [Link]
       
§§§ “Complexes of [(dadi)​Ti(L​/X)​]​m That Reveal Redox Non-​Innocence and a Stepwise Carbene Insertion into a Carbon-​Carbon Bond“
               Heins, S. P.; Morris, W. D.; Cundari, T. R.; MacMillan, S. N.; Lobkovsky, E. B.; Livezey, N. M.; Wolczanski, P. T. Organometallics 2018, 37, 3488-3501. [Link]
       
§§§ “Dispersion forces play a role in (Me2IPr)​Fe(NAd)​R2 (Ad = adamantyl; R = neoPe, 1-​nor) insertions and Fe-​R bond dissociation enthalpies (BDEs)“
               Cundari, T. R.; Jacobs, B. P.; MacMillan, S. N.; Wolczanski, P. T. Dalton Transactions 2018, 47, 6025-6030. [Link]
       
§§§ “Activation of Carbon-​Hydrogen Bonds via 1,​2-​RH-​Addition​/-​Elimination to Early Transition Metal Imides“
               Wolczanski P. T. Organometallics 2018, 37, 505-516. [Link]
       
§§§ “Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe-C Covalency in (Me2IPr)Fe(=NAd)R2 (R = neoPe, 1-nor)“
               Jacobs, B. P.; Wolczanski P. T.; Jiang, Q.; Cundari, T. R.; MacMillan, S. N. J. Am. Chem. Soc. 2017 139, 12145-12148. [Link]
          

 

§§§ “Redox Non-Innocence Permits Catalytic Nitrene Carbonylation by (dadi)Ti=NAd (Ad = Adamantyl)”
               Heins, S. P.; Wolczanski P. T.; Cundari, T. R.; MacMillan, S. N. Chem. Sci. 2017, 8 ,3410-3418. [Link]
          
§§§ “High- and low-spin chelate complexes of iron featuring k-C,X-CH2C6H4X (X ¼ NMe2, PMe2, PPh2) and k-C,P-CH2PMe2 ligands”
               Jacobs, B. P.; Wolczanski, P. T.; MacMillan, S. N. Journal of Organometallic Chemistry, (2017), 847, 132-139. [Link]
          

 

§§§ “Flipping the Oxidation State Formalism: Charge Distribution in Organometallic Complexes As Reported by Carbon Monoxide”
               Wolczanski P. T. Organometallics 2017, 36, 622-631. [Link]
          
§§§  “Fe(IV) alkylidenes are actually Fe(II), and a related octahedral Fe(II) “alkylidene” is a conjugated vinyl complex”
                Jacobs, B. P.; Agarwal, R. G.;Wolczanski, P. T.;Cundari, T. R.; MacMillan, S. N. Polyhedron 2016, 116, 47-56. [Link]
          
§§§  “Application of 93Nb NMR Spectroscopy to (silox)3Nb(Xn/Lm) Complexes (silox = tBu3SiO): Where Does (silox)3Nb(NN)Nb(silox)3 Appear?”
               Hulley, E. B.; Williams, V. A.; Hirsekorn, K. F.; Wolczanski, P. T.; Lancaster, K. M.; Lobkovsky, E.M. Polyhedron 2016, 103, 1105-114. [Link]
          
§§§  “Oxidatively Triggered Carbon–Carbon Bond Formation in Ene-amide Complexes”
                Jacobs, B.P.; Wolczanski, P.T.; Lobkovsky, E.M. Inorg. Chem. 2016, 55, 4223-4232. [Link]
          Presentation1

 

§§§  “Neutral Fe(IV) alkylidenes, Including Some That Bind Dinitrogen”
               Lindley, B.M.; Jacobs, B.P.; MacMillan, S.N.; Wolczanski, P.T. Chem. Comm. 2016, 52, 3891-3894. [Link]
          
§§§  “Nitrene Insertion Into C-C and C-H Bonds of Diamide Diimine Ligands Ligated to Chromium and Iron”
               Heins, S. P.; Morris, W. D.; Wolczanski, P. T.; Lobkovsky, E.B.; Cundari, T.R. Angew. Chem. Int. Ed. 2015, 54, 14407-14411. [Link]
          Presentation1
 §§§  “Fe(IV) alkylidenes via Protonation of Fe(II) Vinyl Chelates and a Comparitive Mossbaurer Spectroscopic Study”
               Lindley, B.M.; Swidan, A.; Lobkovsky, E.B. ;Wolczanski, P.T.; Adelhardt, M.; Sutter, J.; Meyer, K. Chem. Sci., 2015, 6, 4730-4736. [Link]Graphical abstract: Fe(iv) alkylidenes via protonation of Fe(ii) vinyl chelates and a comparative Mössbauer spectroscopic study
§§§ “Iron and Chromium Complexes Containing Tridentate Chelates Based on Nacnac and Imino- and Methyl-Pyridine Components: Triggering C-X Bond Formation”.
               Morris, W. D.; Wolczanski, P. T.; Sutter, J; Meyer, K.; Cundari, T. R.; Lobkovsky, E. B. Inorg Chem. 2014, 53, 7464-7484. [Link]
 ic-2014-00807y_0024
§§§ “Iron Complexes Derived from {nacnac-(CH2py)2}− and {nacnac-(CH2py)(CHpy)}n Ligands: Stabilization of Iron(II) via Redox Noninnocence”.
              Williams, Valerie A.; Wolczanski, Peter T.; Sutter, Jörg; Meyer, Karsten; Lobkovsky, Emil B.; Cundari, Thomas R. Inorg. Chem. 2014, 53, 4459-4474. [Link]
 ic-2014-001123_0001
 §§§ “Exploring the Limits of Redox Non-Innocence: Pseudo Square Planar [{κ4-Me2C(CH2N:CHpy)2}Ni]n (n = 2+, 1+, 0, -1, -2) Favor Ni(II)”.
               Williams, Valerie A.; Hulley, Elliott B.; Wolczanski, Peter T.; Lancaster, Kyle M.; Lobkovsky, Emil B. Chem. Sci. 2013, 4, 3636-3648. [Link]
 2
 §§§ “Lewis Bases Trigger Intramolecular CH-Bond Activation: (tBu3SiO)2W=NtBu <==> (tBu3SiO)(κO,κC-tBu2SiOCMe2CH2)HW=NtBu”.
               Marshak, Michael P.; Rosenfeld, Devon C.; Morris, Wesley D.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Cundari, Thomas R. Eur. J. Inorg. Chem. 2013, 4056-4067. [Link]
 §§§ “C-C Bond Formation and Related Reactions at the CNC Backbone in (smif)FeX (smif = 1,3-Di-(2-pyridyl)-2-azaallyl): Dimerizations, 3 + 2 Cyclization, and Nucleophilic Attack; Transfer Hydrogenations and Alkyne Trimerization (X = N(TMS)2, dpma = (Di-(2-pyridyl-methyl)-amide))”.
               Frazier, Brenda A.; Williams, Valerie A.; Wolczanski, Peter T.; Bart, Suzanne C.; Meyer, Karsten; Cundari, Thomas R.; Lobkovsky, Emil B. Inorg. Chem. 2013, 52, 3295-3312. [Link]
 3
 §§§ “Selective Extraction of N2 from Air by Diarylimine Iron Complexes”.
               Bartholomew, Erika R.; Volpe, Emily C.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Cundari, Thomas R. J. Am. Chem. Soc. 2013, 135, 3511-3527. [Link]
 4
 §§§ “Syntheses and Characterizations of α-Iminopyridine Compounds (alkylNCHpy)2Fe(L/Xn), and an Assessment of Redox Non-Innocence”.
                Volpe, Emily C.; Wolczanski, Peter T.; Darmon, Jonathan M.; Lobkovsky, Emil B. Polyhedron 2013, 52, 406-415. [Link]
 5
 §§§ “Synthetic Approaches to (smif)2Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) Reveal Redox Non-Innocence and C-C Bond-Formation”.
               Frazier, Brenda A.; Wolczanski, Peter T.; Keresztes, Ivan; DeBeer, Serena; Lobkovsky, Emil B.; Pierpont, Aaron W.; Cundari, Thomas R. Inorg. Chem. 2012, 51, 8177-8186. [Link]
 6
 §§§ “A Theoretical Study of the 3d-M(smif)2 Complexes: Structure, Magnetism, and Oxidation States”.
               Hachmann, Johannes; Frazier, Brenda A.; Wolczanski, Peter T.; Chan, Garnet Kin-Lic. ChemPhysChem 2011, 12, 3236-3244. [Link]
 §§§ “Alkane Binding Implicated in Reactions of (tBu3SiN:)3WHK and Alkyl Halides”.
               Schafer, D. F.; Wolczanski, P. T.; Lobkovsky, E. B. Organometallics 2011, 30, 6518-6538. [Link]
 7
 §§§ “Carbon Dioxide Reduction by Early Metal Compounds: A Propensity of Oxygen Atom Transfer”.
               Williams, V. A.; Manke, D. R.; Wolczanski, P. T.; Cundari, T. R. Inorg. Chim. Acta 2011, 369, 203-214. [Link]
 8
 §§§ “Carbon-Carbon Bond Formation from Azaallyl and Imine Couplings about Metal-Metal Bonds”.
               Hulley, E. B.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 2011, 133, 18058-18061. [Link]
  8
 §§§ “Reactivity Studies of (tBu3SiNH)(tBu3SiN:)2WH Including Anionic Derivatives Featuring the Tris-tri-tert-butylsilylimide Tungsten Core”.
               Schafer, D. F.; Wolczanski, P. T.; Lobkovsky, E. B. Organometallics 2011, 30, 6539-6561. [Link]
 9
 §§§ “Synthesis and Characterization of (smif)2Mn n = 0, M = V, Cr, Mn, Fe, Co, Ni, Ru; n = +1, M = Cr, Mn, Co, Rh, Ir; Smif = 1,3-di-(2-pyridyl)-2-azaallyl)”.
               Frazier, B. A.; Bartholomew, E. R.; Wolczanski, P. T.; DeBeer, S.; Santiago-Berrios, M.; Abruna, H. D.; Lobkovsky, E. B.; Bart, S. C.; Mossin, S.; Meyer, K.; Cundari, T. R. Inorg. Chem. 2011, 50, 12414-12436. [Link]
 10
 §§§ “Aryl-Containing Pyridine-Imine and Azaallyl Chelates of Iron Toward Strong Field Coordination Compounds”.
               Volpe, E. C.; Wolczanski, P. T.; Lobkovsky, E. B.Organometallics 2010, 29, 364-377. [Link]
 11
 §§§ “Aryl-Oxazoline Chelates of First-Row Transition Metals: Structures of {κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)]FeCl(py) and [{κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}Cr(μ-Cl)]2“.
               Volpe, E. C.; Manke, D. R.; Bartholomew, E. R.; Wolczanski, P. T.; Lobkovsky, E. B.Organometallics 2010, 29, 6642-6652. [Link]
 12
 §§§ “Pnictogen-Hydride Activation by (silox)3Ta (silox = tBu3SiO); Attempts to Circumvent the Constraints of Orbital Symmetry in N2 Activation”.
               Hulley, E. B.; Bonanno, J. B.; Wolczanski, P. T.; Cundari, T. R.; Lobkovsky, E. B. Inorg. Chem. 2010, 49, 8524-8544. [Link]
 13
 §§§ ” [(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)”.
               Hulley, E. B.; Wolczanski, P. T.; Lobkovsky, E. B. Chem. Commun. 2009, 42, 6412-6414. [Link]
 14
 §§§ “Aryl-Containing Chelates and Amine Debenzylation to Afford 1,3-Di-2-pyridyl-2-azaallyl (smif): Structures of {κ-C,N,Npy2-(2-pyridylmethyl)2N(CH2(4-tBu-phenyl-2-yl))}FeBr and (smif)CrN(TMS)2“.
               Frazier, B. A.; Wolczanski, P. T.; Lobkovsky, E. B. Inorg. Chem. 2009, 48, 11576-11585. [Link]
 15
 §§§ “Structure and reactivity studies of transition metals ligated by tBu3SiX (X = O, NH, N, S, and CC)”.
               Wolczanski, P. T. Chem. Commun. 2009, 7, 740-757. [Link]
 §§§ “Unusual Electronic Features and Reactivity of the Dipyridylazaallyl Ligand: Characterizations of (smif)2M [M = Fe, Co, Co+, Ni; smif = {(2-py)CH}2N] and [(TMS)2NFe]2(smif)2“.
               Frazier, B. A.; Wolczanski, P. T.; Lobkovsky, E. B.; Cundari, T. R. J. Am. Chem. Soc. 2009, 131, 3428-3429. [Link]
 29
 §§§ “Four-Coordinate Mo(II) as (silox)2Mo(PMe3)2 and Its W(IV) Congener (silox)2HW(η2-CH2PMe2)(PMe3) (silox = tBu3SiO)”.
               Kuiper, D. S.; Wolczanski, P. T.; Lobkovsky, E. B.; Cundari, T. R. Inorg. Chem. 2008, 47, 10542-10553. [Link]
 16
 §§§ “Low coordinate, monomeric molybdenum and tungsten(III) complexes: structure, reactivity and calculational studies of (silox)3Mo and (silox)3ML (M = Mo, W; L = PMe3, CO; silox = tBu3SiO)”.
               Kuiper, D. S.; Wolczanski, P. T.; Lobkovsky, E. B.; Cundari, T. R. J. Am. Chem. Soc. 2008, 130, 12931-12943. [Link]
 17
 §§§ “Molybdenum and tungsten structural differences are dependent on ndz2/(n + 1)s mixing: comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)”.
               Kuiper, D. S.; Douthwaite, R. E.; Mayol, A. -R.; Wolczanski, P. T.; Lobkovsky, E. B.; Cundari, T. R.; Lam, O. P.; Meyer, K. Inorg. Chem. 2008, 47, 7139-7153. [Link]
 18
 §§§ “Olefin substitution in (silox)3M(olefin) (silox = tBu3SiO; M = Nb, Ta): the role of density of states in second vs third row transition metal reactivity”.
               Hirsekorn, K. F.; Hulley, E. B.; Wolczanski, P. T.; Cundari, T. R. J. Am. Chem. Soc. 2008, 130, 1183-1196. [Link]
 19
 §§§ “Evidence for Strong Tantalum-to-Boron Dative Interactions in (silox)3Ta(BH3) and (silox)3Ta(η2-B,Cl-BCl2Ph) (silox = tBu3SiO)”.
               Bonanno, J. B.; Henry, T. P.; Wolczanski, P. T.; Pierpont, A. W.; Cundari, T. R. Inorg Chem 2007, 46, 1222-1232. [Link]
 20
 §§§ “Heterolytic CH-bond activation in the synthesis of Ni{(2-aryl-κC2)pyridine-κN}2 and derivatives”.
               Volpe, E. C.; Chadeayne, A. R.; Wolczanski, P. T.; Lobkovsky, E. B. J. Organomet. Chem. 2007, 692, 4774-4783. [Link]
 21
 §§§ “Synthesis and Reactivity of [(silox)2Mo:NR]2Hg (R = tBu, tAmyl; silox = OSitBu3): Unusual Thermal Stability and Ready Nucleophilic Cleavage Rationalized by Electronic Factors”.
               Rosenfeld, D. C.; Wolczanski, P. T.; Barakat, K. A.; Buda, C.; Cundari, T. R.; Schroeder, F. C.; Lobkovsky, E. B. Inorg. Chem. 2007, 46, 9715-9735. [Link]
 22
 §§§ “Aggregation of [(tBu3SiS)MX]: Structures of {[Br2Fe(μ-SSitBu3)2FeBr(THF)]Na(THF)4}∞, cis-[(THF)FeI]2(μ-SSitBu3)2, [(tBu3SiS)Fe]2(μ-SSitBu3)2, and Comparative Structure and Magnetism Studies of [(tBu3SiS)MX]n (M = Fe, Co, X = Cl, n = 12; M = Fe, Ni, X = Br, n = 12; M = Fe, X = I, n = 14)”.
               Sydora, O. L.; Henry, T. P.; Wolczanski, P. T.; Lobkovsky, E. B.; Rumberger, E.; Hendrickson, D. N. Inorg. Chem. 2006, 45, 609-626. [Link]
 23
 §§§ “PC Bond Cleavage of (silox)3NbPMe3 (silox = tBu3SiO) under Dihydrogen Leads to (silox)3Nb:CH2, (silox)3Nb:PH or (silox)3NbP(H)Nb(silox)3, and CH4”.
               Hirsekorn, Kurt F.; Veige, Adam S.; Wolczanski, Peter T. J. Am. Chem. Soc. 2006, 128, 2192-2193. [Link]
 24
 §§§ “Synthesis and Reactivity of (silox)2R2WO (R = Cl, Me, Et, nPr and nBu; silox = OSitBu3) and (silox)2MO2 (M = Mo and W)”.
               Rosenfeld, Devon C.; Kuiper, David S.; Lobkovsky, Emil B.; Wolczanski, Peter T. Polyhedron 2006, 25, 251-258. [Link]
 25
 §§§ “The Butterfly Dimer [(tBu3SiO)Cr]2(μ-OSitBu3)2 and Its Oxidative Cleavage to (tBu3SiO)2Cr(:N-N:CPh2)2 and (tBu3SiO)2Cr:N(2,6-Ph2-C6H3)”.
               Sydora, Orson L.; Kuiper, David S.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Dinescu, Adriana; Cundari, Thomas R. Inorg. Chem. 2006, 45, 2008-2021. [Link]
 26
 §§§ “Covalent Attachment of a Transition Metal Coordination Complex to Functionalized Oligo(phenylene-ethynylene) Self-Assembled Monolayers”.
               Dube, Abhishek; Chadeayne, Andrew R.; Sharma, Manish; Wolczanski, Peter T.; Engstrom, James R. J. Am. Chem. Soc. 2005, 127, 14299-14309. [Link]
 27
 §§§ “3-Center-4-Electron Bonding in [(silox)2Mo:NtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate”.
               Rosenfeld, Devon C.; Wolczanski, Peter T.; Barakat, Khaldoon A.; Buda, Corneliu; Cundari, Thomas R. J. Am. Chem. Soc. 2005, 127, 8262-8263. [Link]
 28
 §§§ “Low-Coordinate Chromium Siloxides: The “Box” [Cr(μ-Cl)(μ-OSitBu3)]4, Distorted Trigonal [(tBu3SiO)3Cr][Na(benzene)] and [(tBu3SiO)3Cr][Na(dibenzo-18-c-6)], and Trigonal (tBu3SiO)3Cr”.
               Sydora, Orson L.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Buda, Corneliu; Cundari, Thomas R. Inorg. Chem.  2005, 44, 2606-2618. [Link]
 30
 §§§ “Thermodynamics, Kinetics, and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta)”.
               Hirsekorn, Kurt F.; Veige, Adam S.; Marshak, Michael P.; Koldobskaya, Yelena; Wolczanski, Peter T.; Cundari, Thomas R.; Lobkovsky, Emil B. J. Am. Chem. Soc. 2005, 127, 4809-4830. [Link]
 31
 §§§ “Transition Metal Complexes of Cyclic and Open Ozone and Thiozone”.
               Flemmig, Beate; Wolczanski, Peter T.; Hoffmann, Roald. J. Am. Chem. Soc. 2005, 127, 1278-1285. [Link]
 32
 §§§ “Syntheses and Electrochemistry of (p-XC6H4O)6W (1-X, X=H, CH3, OCH3, Cl, Br, OH, OCH2Ph) and (p-XC6H4O)5W(OC6H4OH) (X = H, CH3, OCH3, Cl, Br): an Approach to Electrocatalytic CH Bond Activation”.
               Sydora, Orson L.; Goldsmith, Jonas I.; Vaid, Thomas P.; Miller, Abigail E.; Wolczanski, Peter T.; Abruna, Hector D. Polyhedron 2004, 23, 2841-2856. [Link]
 33
 §§§ “The Course of (R2R’SiO)3TaCl2 (R = tBu, R’ = H, Me, Ph, tBu (silox); R = iPr, R’ = tBu, iPr) Reduction Is Dependent on Siloxide Size”.
               Chadeayne, Andrew R.; Wolczanski, Peter T.; Lobkovsky, Emil B. Inorg. Chem. 2004, 43, 3421-3432. [Link]
 34
 §§§ “First Row Wheels, {(tBu3SiS)MX}12 (M = Co, X = Cl; M = Ni, X = Br), are Common Amongst Both Simpler and More Complex Aggregates”.
               Sydora, Orson L.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Rumberger, Evan; Hendrickson, David N. Chem. Commun. 2004, 6, 650-651. [Link]
 35
 §§§ “Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)3WNO and R3PO (R = Me, Ph, tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-Picoline), Ta; silox = tBu3SiO)”.
               Veige, Adam S.; Slaughter, LeGrande M.; Lobkovsky, Emil B.; Wolczanski, Peter T.; Matsunaga, Nikita; Decker, Stephen A.; Cundari, Thomas R. Inorg. Chem. 2003, 42, 6204-6224. [Link]
 36
 §§§ “Ferrous Wheels, Ellipse [(tBu3SiS)FeX]n, and Cube [(tBu3SiS)Fe(CCSitBu3)]4”.
               Sydora, Orson L.; Wolczanski, Peter T.; Lobkovsky, Emil B. ACIE 2003, 42, 2685-2687. [Link]
 37
 §§§ “Amide Derivatives of Tantalum and a Niobium-Promoted Ring Opening of 3,5-Lutidine”.
               Bonanno, Jeffrey B.; Veige, Adam S.; Wolczanski, Peter T.; Lobkovsky, Emil B. Inorg. Chim. Acta 2003, 345, 173-184. [Link]
 38
 §§§ “Ethylene and Alkyne Carbon-Carbon Bond Cleavage across Tungsten-Tungsten Multiple Bonds”.
               Chamberlin, Rebecca L. M.; Rosenfeld, Devon C.; Wolczanski, Peter T.; Lobkovsky, Emil B. Organometallics 2002, 21, 2724-2735. [Link]
 39
 §§§ “Carbon-Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C-H Activation”.
              Cundari, Thomas R.; Klinckman, Thomas R.; Wolczanski, Peter T. J. Am. Chem. Soc. 2002, 124, 1481-1487. [Link]
 40
 §§§ “(silox)3RePMe3 (silox = tBu3SiO) is Carbonylated to the Double Insertion Product (silox)(Me3P){cis-(CO)2}Re{trans-(CO2SitBu3)2}”.
               Veige, Adam S.; Wolczanski, Peter T.; Lobkovsky, Emil B. Chem. Commun. 2001, 24, 2734-2735. [Link]
 §§§ “Dehydrogenation of [{(silox)3Nb}2(η-1,2;η-5,6-C8H8)] (silox = tBu3SiO) to [{(silox)3Nb}2(η-1,2;η-5,6-C8H6)] and its Subsequent Alkene-to-Alkylidene Rearrangement”.
               Veige, Adam S.; Wolczanski, Peter T.; Lobkovsky, Emil B. ACIE 2001, 40, 3629-3632. [Link]
 41
 §§§ “Synthesis of (tBu3SiNH)2ClW≡WCl(NHSitBu3)2 and Its Degradation via NH Bond Activation”.
               Holmes, Stephen M.; Schafer, Daniel F., II; Wolczanski, Peter T.; Lobkovsky, Emil B. J. Am. Chem. Soc. 2001, 123, 10571-10583. [Link]
 §§§ “Hydrogen Bonds Between Polyphenol (p-HOC6H4O)6W and Bipyridines: (4,4′-bipy·HOC6H4O)6W and 3-D Networks [{4,4′-(NC5H4)2(CH2CH2)}n{(HOC6H4O)6W}]∞ (n = 2, 3)”.
               Vaid, Thomas P.; Sydora, Orson L.; Douthwaite, Richard E.; Wolczanski, Peter T.; Lobkovsky, Emil B. Chem. Commun. 2001, 14, 1300-1301. [Link]
 §§§ “Deoxygenations of (silox)3WNO and R3PO by (silox)3M (M = V, Ta) and (silox)3NbL (silox = tBu3SiO): Consequences of Electronic Effects”.
               Veige, Adam S.; Slaughter, Lee M.; Wolczanski, Peter T.; Matsunaga, Nikita; Decker, Stephen A.; Cundari, Thomas R. J. Am. Chem. Soc. 2001, 123, 6419-6420. [Link]
 §§§ “Insertion of H2C:CHX (X = F, Cl, Br, OiPr) into (tBu3SiO)3TaH2 and β-X-Elimination from (tBu3SiO)3HTaCH2CH2X (X = OR): Relevance to Ziegler-Natta Copolymerizations”.
               Strazisar, Stephanie A.; Wolczanski, Peter T. J. Am. Chem. Soc. 2001, 123, 4728-4740.
  §§§ “Covalent Titanium Aryldioxy One-, Two-, and Three-Dimensional Networks and Their Examination as Ziegler-Natta Catalysts”.
               Tanski, Joseph M.; Wolczanski, Peter T. Inorg. Chem. 2001, 40, 2026-1033.
  §§§ “A Covalent Vanadium(III) 2-Dimensional Network and Vanadyl Chains Linked by Aryldioxides”.
                Tanski, Joseph M.; Wolczanski, Peter T. Inorg. Chem. 2001, 40, 346-353.
  §§§ “Covalent Metal-Organic Networks: Pyridines Induce 2-Dimensional Oligomerization of (μ-OC6H4O)2Mpy2 (M = Ti, V, Zr)”.
               Tanski, Joseph M.; Vaid, Thomas P.; Lobkovsky, Emil B.; Wolczanski, Peter T. Inorg. Chem. 2000, 39, 4756-4765.
  §§§ “Inter- and Intramolecular Experimental and Calculated Equilibrium Isotope Effects for (silox)2(tBu3SiND)TiR + RH (silox = tBu3SiO): Inferred Kinetic Isotope Effects for RH/D Addition to Transient (silox)2Ti:NSitBu3”.
               Slaughter, LeGrande M.; Wolczanski, Peter T.; Klinckman, Thomas R.; Cundari, Thomas R. J. Am. Chem. Soc. 2000, 122, 7953-7975.
  §§§ “Covalent Titanium(IV)-Aryloxide Network Materials: 4,4′-Biphenoxide 3D and Polyphenolic 2D Motifs”.
               Tanski, Joseph M.; Lobkovsky, Emil B.; Wolczanski, Peter.  J. Solid State Chem. 2000, 152, 130-140.
  §§§ “(Silox)3Nb(η2-N,C-4-picoline) as a Source of (silox)3Nb: Structure of [(silox)3Nb]2(μ-η2,η2-C6H6) (silox = tBu3SiO)”.
               Veige, A. S.; Kleckley, T. S.; Chamberlin, R. M.; Neithamer, D. R.; Lee, C. E.; Wolczanski, P. T.; Lobkovsky, E. B.; Glassey, W. V. J. Organomet. Chem. 1999, 591, 194-203.
  §§§ “Covalent Three-Dimensional Titanium(IV)-Aryloxide Networks”.
               Vaid, Thomas P.; Tanski, Joseph M.; Pette, John M.; Lobkovsky, Emil B.; Wolczanski, Peter T. Inorg. Chem. 1999, 38, 3394-3405.
  §§§ “[(Silox)2ReO]2 (silox = tBu3SiO) Contains a Re≡Re Bond and Terminal Oxo Ligands”.
               Douthwaite, Richard E.; Wolczanski, Peter T.; Merschrod, Erika. Chem. Commun. 1998, 23, 2591-2592.
  §§§ “Structural Dichotomy in Six-Coordinate d0 Complexes: Trigonal Prismatic (tBu3SiC≡C)6Ta- and Octahedral (tBu3SiC≡C)6M2- (M = Zr, Hf)”.
               Vaid, Thomas P.; Veige, Adam S.; Lobkovsky, Emil B.; Glassey, Wingfield V.; Wolczanski, Peter T.; Liable-Sands, Louise M.; Rheingold, Arnold L.; Cundari, Thomas R. J. Am. Chem. Soc. 1998, 120, 10067-10079.
  §§§ “d0 Alkane Complexes (tBu3SiN:)3W(RH) Precede C-H Activation and Formation of (tBu3SiN:)2(tBuSiNH)WR/R’”.
               Schafer, Daniel F., II; Wolczanski, Peter T. J. Am. Chem. Soc. 1998, 120, 4881-4882.
  §§§ “Extracting Absolute Titanium-Alkyl and -Hydride Bond Enthalpies from Relative D(TiR(H)) in (silox)2(tBu3SiNH)TiR: Electronegativity and ECT Models”.
               Bennett, Jordan L.; Vaid, Thomas P.; Wolczanski, Peter T. Inorg. Chim. Acta 1998, 270, 414-423.
  §§§ “Ti(μ:η1,η1-OCMe2CH2PPh2)3Rh has a Cylindrically Symmetric Triple Bond”.
               Slaughter, LeGrande M.; Wolczanski, Peter T. Chem. Commun. 1997, 21, 2109-2110.
  §§§ “Selectivities in Hydrocarbon Activation: Kinetic and Thermodynamic Investigations of Reversible 1,2-RH-Elimination from (silox)2(tBu3SiNH)TiR (silox = tBu3SiO)”.
                Bennett, Jordan L.; Wolczanski, Peter T. J. Am. Chem. Soc. 1997, 119, 10696-10719.
  §§§ “Carbon-Oxygen and Related R-X Bond Cleavages Mediated by (silox)3Ti and Other Group 4 Derivatives (silox = tBu3SiO)”.
               Covert, Katharine J.; Mayol, Ana-Rita; Wolczanski, Peter T. Inorg. Chim. Acta 1997, 263, 263-278.
  §§§ “Covalent 3- and 2-Dimensional Titanium-Quinone Networks”.
               Vaid, Thomas P.; Lobkovsky, Emil B.; Wolczanski, Peter T. J. Am. Chem. Soc. 1997, 119, 8742-8743.
  §§§ “Pyridine C:N Bond Cleavage Mediated by (silox)3Nb (silox = tert-Bu3SiO)”.
               Kleckley, Troy S.; Bennett, Jordan L.; Wolczanski, Peter T.; Lobkovsky, Emil B. J. Am. Chem. Soc. 1997, 119, 247-248.
  §§§ “Conversion of [(tBuCH2)2TaN]5 to Cubic TaN: Related Syntheses, EHMO Calculations, and MAS and Spin Echo 15N NMR Spectroscopies”.
               Banaszak Holl, Mark M.; Wolczanski, Peter T.; Proserpio, Davide; Bielecki, Anthony; Zax, David B. Chem. Mater. 1996, 8, 2468-2480.
  §§§ “Arylamine C-N Bond Oxidative Addition to (siloxy)3Ta (siloxy = tBu3SiO)”.
               Bonanno, Jeffrey B.; Henry, Thomas P.; Neithamer, David R.; Wolczanski, Peter T.; Lobkovsky, Emil B. J. Am. Chem. Soc. 1996, 118, 5132-5133.